Wave Aspect of Matter

The De Broglie Wavelength

A particle is described as a frequency ν and a wave fector k. E=hν=ω,p=k=2πλk^.

ψ(r,t)=Aexpi(ωtkr).

λ=h/p. For non-relativistic cases, λ=h/(mv).

Statistical Interpretation, the Wave Function

  1. Classical Trajectory Time-varying state
  2. Quantum States Wave function ψ(r,t,)
  3. ψ(r,t) is the Probability Amplitude
  4. Probability to find a particle at t in volume d3r=dxdydz is dP(r,t)=C|ψ(r,t)|2d3r. |ψ|2 is a Probability Density
  5. Principle of spectral decomposition (Superposition of states) Measure A eigenstates of A, {(ai,ψi(r))}. ψ(r,t0)=ψa1(r)a1 and the wavefunction will remain in the state. Mixed states give a spectral decomposition of eigenstates, ψ(r,t0)=acaψa(r), Pa=|ca|2a|ca|2,aPa=1. Measure A, get a1 implies the state is now ψa1(r).
  6. Schrödinger equation. H^Ψ=EΨ. Where H^ is the Hamiltonian of the system. Square-integrable, continuous, finite, |ψ(r,t)|2d3r=1.

Author: Christian Cunningham

Created: 2024-05-30 Thu 21:16

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